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LCOS Strasbourg - Publications du Groupe english version
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2012
120. Intramolecular reductive ketone-alkynoate coupling reaction promoted by (η2-propene)titanium
Schäfer, C.; Miesch, M.; Miesch, L. Org. Biomol. Chem, 2012, 10, 3253-3257. DOI: 10.1039/C2OB07049A


119. Access to Polyfunctionalized Diquinanes, Hydrindanes, and Decalines via TiCl4 Promoted Michael-Aldol and Baylis-Hillman Reactions
Ressault, B.; Jaunet, A.; Geoffroy, P.; Goudedranche, S.; Miesch, M. Org. Lett., 2012, 14, 366-369. DOI: 10.1021/ol203118t


2011
118. Conjugate Reduction and Reductive Aldol Cyclization of α,β-Unsaturated Thioesters Catalyzed by (BDP)CuH.
Li, N.; Ou, J.; Miesch, M.; Chiu, P. Org. Biomol. Chem., 2011, 9, 6143-6147. DOI: 10.1039/C1OB05352C


117. Norrish-Prins reaction as a key step in the synthesis of 14β-hydroxy-5Hα (or 5Hβ or Δ5,6)-pregnane derivatives.
Geoffroy, P., Ressault, B., Marchioni, E., Miesch, M. Steroids 2011, 76, 1166-1175. DOI: 10.1016/j.steroids.2011.05.004


116. Camara, B. ; Bouvier, F. ; Heintz, D. ; Geoffroy, P.; Miesch, M. « Caractérisation de nouvelles molécules terpéniques modulant le développement des plantes » French Patent Application N° 11551594 du 14/06/2011

115. Mensah-Nyagan, A. G. ; Meyer, L. ; Patte-Mensah, C. ; Taleb, O. ; Miesch, M. ; Geoffroy, P. ; Ressault, B. « Dérivés de l'alloprégnanolone et de l'épialloprégnanolone et leurs utilisations pour traiter un état neuropathologique » French Patent Application N° 1152390 du 23/03/2011

114. Synthesis of Hoodigogenin A, aglycone of a natural appetite suppressant glycosteroids extracted from Hoodia gordonii.
Geoffroy, P., Ressault, B., Marchioni, E., Miesch, M. Steroids 2011, 76, 702-708. DOI: 10.1016/j.steroids.2011.03.014


113. Stereoselective Synthesis of 3-Amino-3-deoxy-aldohexoses by Aldol Condensation of Tricarbonyliron-α-Aminodienone Complexes: Total Synthesis of Multiprotected Kanosamine.
Miesch, L; Welsch, T., Toupet, L. Synthesis 2011, 1, 161-167. DOI: 10.1055/s-0030-1258320


2010
112. Geoffroy, P.; Ressault, B. ; Miesch , M. « Procédé de synthèse de stéroides » French Patent Application N° 10 03194 du 29/07/2010

111. Anionic Cascade Reaction Followed by Silylative Dieckmann Cyclisation: a Straightforward Route to Tricyclic Fused Ring Systems Starting from Alkynyl Esters Tethered to Bicyclo[n.2.0]Alkanones.
Rietsch, V.; Miesch, L.; Yamashita, D.; Miesch, M. Eur. J. Org. Chem. 2010, 36, 6944-6948. DOI: 10.1002/ejoc.201000986


110. Domino Reactions Starting From Alkynyl Esters Tethered To 2-Methyl-1,3-Cycloalkanediones. Efficient Access To Polyfunctionalized Diquinanes, Allenoates And Oxetanes.
Geoffroy, P.; Ballet, M-P.; Finck, S.; Marchioni, E.; Miesch, M. Tetrahedron 2010, 66, 7012-7016. DOI: 10.1016/j.tet.2010.06.025


109. Synthesis of racemic and enantiomerically pure acetylenic ω-ketoesters.
Geoffroy, P.; Ballet, M-P.; Finck, S.; Marcic, C.; Marchioni, E.; Miesch, M. Synthesis 2010, 1, 171-179. DOI: 10.1055/s-0029-1217043

2009
108. Diastereomeric (η4-diene)Fe(CO)3 Complexes Containing Chiral Amide Groups: a Convenient Method for the Resolution of Amino Acids.
Schumacher, M.; Coste, G.; Miesch, L. Synthesis 2009, 6, 1014-1020. DOI: 10.1055/s-0028-1083370


107. Intramolecular alkynylogous Mukaiyama aldol reaction starting from bicyclic alkanones tethered to alkynyl esters: formal total synthesis of (±)-Hamigeran B.
Miesch, L.; Welsch, T.; Rietsch, V.; Miesch, M. Chem. Eur. J. 2009, 15, 4394-4401. DOI: 10.1002/chem.200802309

106. Effects of oxidation on the hydrolysis by cholesterol esterase of sitosteryl esters as compared to a cholesteryl ester.
Julien-David, D.; Ennahar, S.; Miesch, M.; Geoffroy, P.; Raul, F.; Aoude-Werner, D.; Lessinger, J-M.; Marchioni, E. Steroids 2009, 74, 832-836. DOI: 10.1016/j.steroids.2009.05.003

2008
105. Synthesis of highly pure oxyphytosterols and (oxy)phytosterol esters. Part II. (Oxy)-sitosterol esters derived from oleic acid and from 9,10-dihydroxystearic acid.
Julien-David, D.; Geoffroy, P.; Marchioni, E.; Raul, F.; Aoude-Werner, D.; Miesch, M Steroids 2008, 73, 1098-1109. DOI: 10.1016/j.steroids.2008.04.010
 

104. Synthesis of highly pure oxyphytosterols and (oxy)phytosterol esters
Geoffroy, P.; Julien-David, D.; Marchioni, E.; Raul, F.; Aoude-Werner, D.; Miesch, M. Steroids 2008, 73, 702-707. DOI: 10.1016/j.steroids.2008.02.004


103
. Intramolecular alkynylogous Mukaiyama aldol type reaction mediated by TBSOTf/NEt3
Miesch, L.; Rietsch, V.; Welsch, T.; Miesch, M. Tetrahedron Lett. 2008, 49, 5053-5055 DOI: 10.1016/j.tetlet.2008.06.038
 

2007
102. Mitochondrial perturbation, oxidative stress and lysosomal destabilization are involved in 7β-hydroxysitosterol and 7β-hydroxycholesterol triggered apoptosis in human colon cancer cells.
Roussi, S.; Gosse, F.; Aoude-Werner, D.; Zhang, X.; Marchioni, E.; Geoffroy, P.; Miesch, M.; Raul, F. Apoptosis 2007, 12, 87-96. DOI: 10.1007/s10495-006-0485-y


101. Toxicological potential of 2-alkylcyclobutanones - specific radiolytic products in irradiated fat-containing food - in bacteria and human cell lines.
Hartwig, A.; Pelzer, A.; Burnouf, D.; Titeca, H.; Delincee, H.; Briviba, K.; Soika, C.; Hodapp, C.; Raul, F.; Miesch, M.; Werner, D.; Horvatovich, P.; Marchioni, E. Food Chem. Toxicol. 2007, 45, 2581-2591. DOI: 10.1016/j.fct.2007.05.033

2006
100. Perturbation of polyamine metabolism and its relation to cell death in human colon cancer cells treated by 7b-hydroxycholesterol and 7b-hydroxysitosterol.
Roussi, S.; Gosse, F.; Aoude-Werner, D.; Zhang, X.; Geoffroy, P.; Miesch, M.; Marchioni, E.; Raul, F. Int. J. Oncol. 2006, 29, 1549-1554. Link

99. Quantitative Analysis of
b -Sitosterol Oxides Induced in Vegetable Oils by Natural Sunlight, Artificially Generated Light, and Irradiation
Zhang, X.; Julien-David, D.; Miesch, M.; Raul, F.; Geoffroy, Ph.; Aoude-Werner, D.; Ennahar, S.; Marchioni, E. J. Agric. Food Chem. 2006, 54, 5410-5415. DOI: 10.1021/jf053224f


98. Asymmetric synthesis of polyfunctionalized allenic esters. Toward the synthesis of an Iphionane sesquiterpene.
Klein, A.; Miesch, M. Synthesis 2006, 2613-2617. DOI: 10.1055/s-2006-942463

97. Separation of
D 5- and D 7-Phytosterols by Adsorption Chromatography and Semipreparative Reversed Phase High-Performance Liquid Chromatography for Quantitative Analysis of Phytosterols in Foods.
Zhang, X.; Cambrai, A.; Miesch, M.; Roussi, S.; Raul, F.; Aoude-Werner, D.; Marchioni, E. J. Agric. Food Chem. 2006, 54, 1196-1202. DOI: 10.1021/jf052761x

96. Determination of 2-Alkylcyclobutanones with Electronic Impact and Chemical Ionization Gas Chromatography/Mass Spectrometry (GC/MS) in Irradiated Foods.
Horvatovich, P.; Werner, D.; Jung, S.; Miesch, M.; Delincee, H.; Hasselmann, C.; Marchioni, E. J. Agric Food Chem., 2006, 54,1990-1996. DOI: 10.1021/jf0524426

95. Natural Products Bearing a Bicyclo[3.2.0]Heptane Skeleton.
Miesch, M. Curr. Org.
Synth. 2006, 3, 327-340. DOI: 10.1002/chin.200716246

2005
94. Determination of Monounsaturated Alkyl Side Chain 2-Alkylcyclobutanones in Irradiated Foods.
Horvatovitch, P.; Miesch, M.; Hasselmann, C.; Delincee, H.; Marchioni, E. J. Agric. Food Chem. 2005, 53, 5836-5841.
DOI: 10.1021/jf050161s

93. Identification and quantitative analysis of b-sitosterol oxides in vegetable oils by capillary gas chromatography–mass spectrometry.
Zhang, X.; Julien-David, D.; Miesch, M.; Geoffroy P.; Raul, F.; Roussi, S.; Aoudé-Werner, D.; Marchioni, E Steroids 2005,70, 896-906.
DOI: 10.1016/j.steroids.2005.06.004

92. Gram-scale chromatographic purification of b-sitosterol. Synthesis and characterization of b-sitosterol oxides.
Zhang, X.; Geoffroy, P.; Miesch, M; Julien-David, D.; Raul, F.; Aoudé-Werner, D.; Marchioni, E. Steroids 2005, 70, 886-895. DOI: 10.1016/j.steroids.2005.06.003


91.Controlled Synthesis of a–Allenic Ester and Spiro Ketone Derivatives from Tailored a-Substituted Cycloalkanones through Cascade Reactions. Exploring the Possible Reaction Pathways by means of Semiempirical MO Calculations
. Mota, A. J.; Klein, A.;  Wendling, F.; Dedieu, A.; Miesch, M. Eur. J. Org. Chem. 2005, 4346-4358. DOI: 10.1002/ejoc.200500339

90. Different apoptotic mechanisms are involved in the antiproliferative effects of 7b-hydroxysitosterol and 7b-hydroxycholesterol in human colon cancer cells.
Roussi, S.; Winter, A.; Gosse, F.; Werner, D.; Zhang, X.; Marchioni, E.; Geoffroy, P.; Miesch, M.; Raul, F. Cell Death Differ. 2005 12, 128–135. DOI: 10.1038/sj.cdd.4401530

2004
89. Inter- and intramolecular carbene reactions of diazoketones tethered to tricarbonyliron coordinated acyclic dienes to tricarbonyliron complexes of cyclohexa-2,4-dienone and cyclopent-2-enone.
M. Franck-Neumann, P. Geoffroy, D. Gassmann, A. Winling Tetrahedron Lett. 2004, 45, 5407-5410.
DOI: 10.1016/j.tetlet.2004.05.052 

88. Toxicological study on 2-alkylcyclobutanones - results of a collaborative study.
Marchioni, E.; F. Raul, F.; Burnouf, D.; Miesch, M.; Delinceee, H.; Hartwigf, A. . Werner, D.;
Rad. Phys. Chem. 2004, 71, 145-148. DOI: 10.1016/j.radphyschem.2004.05.042

87. Article sur invitation du Prof. E. Carreira (ETH Zürich)
Synthesis of
a-allenic esters(acids).
Miesch, M. Synthesis 2004, 746-752. DOI: 10.1055/s-2004-815983

86. Synthesis of bicyclo[4.n.1]alkanones.
Montalt, J.; Linker, F.; Ratel, F.; Miesch, M. J. Org.
Chem. 2004, 69, 6715-6721. DOI: 10.1021/jo048923q

2003
85. Synthesis of tricarbonyliron cyclohexa-2,4-dienone complexes from tosylhydrazones of acyclic dienone complexes. A novel ansa dicarbonyliron complex by intramolecular trapping of reaction intermediates of the cyclocarbonylation reaction.
M. Franck-Neumann, P. Geoffroy, D. Gassmann, C. Cénac J. of Organomet. Chem, 2003, 678, 68-71 DOI: 10.1016/S0022-328X(03)00437-6
 

84. Diene (tricarbonyl) iron complexes linked to spirooxazolones for the synthesis of cyclopropyldihydroxyphenylalanine.
M. Schumacher, L. Miesch, M. Franck-Neumann  Tetrahedron Lett., 2003, 44; 5393-5395. DOI: 10.1016/S0040-4039(03)01312-1

83. New cascade reactions starting from acetylenic w-ketoesters: an easy access to electrophilic allenes and to 1, 3- bridgehead ketones.
Klein, A.; Miesch, M. Tetrahedron Lett., 2003, 44, 4483-4485. DOI: 10.1016/S0040-4039(03)01023-2

82. Photochemical, thermal and base induced ring access to hydroazulene derivatives via two carbon ring enlargement reactions of condensed electrophilic cyclobutenes.
Mislin, G.; Miesch, M. J. Org. Chem., 2003, 68, 433-441. DOI: 10.1021/jo025913l

2002
81. Synthesis of mono- and polycyclic tricarbonyliron cyclohexa-2,4-dienone complexes and phenols from tosylhydrazones of acyclic dienone complexes.
M.Franck-Neumann, P.Geoffroy, D.Gassmann, Synlett, 2002, 12, 2054-58. DOI: 10.1055/s-2002-35598


80. Highly stereoselective biomimetic polyene cyclizations using chiral pentadienol tricarbonyliron complexes.
M.Franck-Neumann, P.Geoffroy, D.Hanss, Tetrahedron Lett. 2002, 43, 2277. DOI: 10.1016/S0040-4039(02)00190-9

79. Conjugate addition of organozinc reagents to enones linked to a tricarbonyl iron diene unit. Asymmetric synthesis of a building block of amphotericin B.
M. Franck-Neumann, L. Miesch, C. Gateau, F. Morin Tetrahedron Lett. 2002, 43, 7635-7638. DOI: 10.1016/S0040-4039(02)01585-X


78. Supercritical fluid extraction for the detection of 2-dodecylcyclobutanone in low dose irradiated plant foods.
Horvatovitch, P.; Miesch, M.; Hasselmann, C.; Marchioni, M. J Chromato A, 2002, 968, 251-255. DOI: 10.1016/S0021-9673(02)00822-1


77. Food -borne radiolytic compounds promote experimental colon carcinogenesis.
F. Raul, F. Gossé, H. Delincée, A. Hartwig, E. Marchioni, M. Miesch, D. Werner, D. Burnouf Nutrition and. Cancer, 2002, 44, 188-191. DOI: 10.1207/S15327914NC4402_11


76. Cyto- und Genotoxizität von 2-Alkylcyclobutanonen.
H. Delincée, C. Soika, C. Hodapp, E. Marchioni, D. Burnouf, M. Miesch, F. Raul, D. Werner, A. Hartwig, G. Rechkemmer Proc. Germ. Nutr. Soc., 2002, 4, 31-32.

75. Detection of 2-alkylcyclobutanones, markers for irradiated foods, in adipose tissues of animals fed with these substances.
P. Horvatovitch, F. Raul, M. Miesch, D. Burnouf, H. Delincée, A. Hartwig, D. Werner, E. Marchioni J. Food Prot., 2002, 65, 1610-1613. Link

74. Efficient reaction pathway for the synthesis of saturated and mono-unsaturated 2-alkylcyclobutanones.
M. Miesch, L. Miesch, P. Horvatovitch, D. Burnouf, H. Delincee, A. Hartwig, F. Raul, D. Werner, E. Marchioni
Radiat. Phys. Chem., 2002, 65, 233-239. DOI: 10.1016/S0969-806X(02)00265-7

73. Detection of low amount of irradiated ingredients in non irradiated precooked meals.
E. Marchioni, P. Horvatovitch, B. Ndiaye, M. Miesch, C. Hasselmann Radiat. Phys. Chem., 2002, 63, 447-450. DOI: 10.1016/S0969-806X(01)00538-2 

2001
72. A new method for the demetallation of tricarbonyliron diene complexes by total hydrogenation with Raney Nickel. Application to a very short synthesis of (+)-[6]-gingediol.
M. Franck-Neumann, P. Bissinger, P. Geoffroy, S. Adelaide
. Tetrahedron Lett. 2001, 42, 640110.1016/S0040-4039(01)01263-1

71. Unexpected reactivity of acetylenic ω-ketoesters toward TBAF and t-BuOK ; new cascade reactions affording allene and oxetane derivatives.
F. Wendling, M. Miesch Org. Lett., 2001, 3, 2689-2691. DOI: 10.1021/ol016263v


70. Synthesis of polyfunctionalized bicyclo[5.3.1]undecadiene ring system using a two carbon ring expansion of cyclobutene intermediates.
G. Mislin, M. Miesch Eur. J. Org. Chem., 2001, 1753-1759. DOI: 10.1002/1099-0690(200105)2001:9<1753::AID-EJOC1753>3.0.CO;2-E

2000
69. Aldol condensation reactions of tricarbonyliron complexes. Towards building blocks for the synthesis of macrolide antibiotics and fluorinated analogs.
M. Franck-Neumann, P. Geoffroy, F. Gumery  Tetrahedron Lett. 2000, 41, 4219. DOI: 10.1016/S0040-4039(00)00569-4


68. Aldol condensation reactions of tricarbonyliron complexes. Easy access to diastereomerically pure 1,2,3-trisubstituted 1,3-diols from α-substituted dienone complexes.
M. Franck-Neumann, P. Geoffroy, F. Gumery, P. Bissinger. Tetrahedron Lett. 2000, 41, 4213. DOI: 10.1016/S0040-4039(00)00568-2


67. Highly stereoselective total synthesis of multiprotected 3-amino-3,6-dideoxy-aldohexoses (mycosamine/mycaminose) by tin triflate mediated aldol condensation reaction of tricarbonyl iron/ α-aminodienone complexes.
M. Franck-Neumann, L. Miesch, C. Gateau  Eur. J. Org. Chem. 2000, 3693-3702. DOI: 10.1002/1099-0690(200011)2000:22<3693::AID-EJOC3693>3.0.CO;2-S


66. Synthesis and fluorescence properties of novel transmembrane probes and determination of their orientation within vesicles.
E. Quesada, M. Ardhammar, B. Norden, M. Miesch, G. Duportail, Y. Bonzi-Coulibaly, Y. Nakatani, G. Ourisson Helv. Chim. Acta, 2000, 83, 2464-2476. DOI: 10.1002/1522-2675(20000906)83:9<2464::AID-HLCA2464>3.0.CO;2-T


65. Uncatalyzed, solvent-free [2+2] cycloaddition of cyclic ketene trimethylsilyl acetals with electrophilic acetylenes.
M. Miesch, F. Wendling Eur. J. Org. Chem., 2000, 3381-3392. DOI: 10.1002/1099-0690(200010)2000:20<3381::AID-EJOC3381>3.0.CO;2-Q


64. Supercritical fluid extraction of hydrocarbons and 2-alkylcyclobutanones for the detection of irradiated foodstuffs.
P. Horvatovitch, M. Miesch, C. Hasselemann, E. Marchioni. J. Chrom. A, 2000, 897, 259-268. DOI: 10.1016/S0021-9673(00)00810-4

1999
63. Cyclization and fluorination of 5-hexenols with boron trifluoride etherate. Stereoselective synhesis of (optically active) fluorinated cyclohexane derivatives by cyclization of ω-pentenyl pentadienol tricarbonyl iron complexes.
M. Franck-Neumann, P. Geoffroy, D. Hanss  Tetrahedron Lett. 1999, 40, 8487. DOI: 10.1016/S0040-4039(99)01797-9


62. Highly stereoselective synthesis of 3-amino-3,6-dideoxy-aldohexoses by tin triflate mediated aldol condensation reaction of tricarbonyl iron α-aminodiene complexes. Total synthesis of multiprotected Mycosamine.
M. Franck-Neumann, L. Miesch-Gross, C. Gateau  Tetrahedron Lett., 1999, 40, 2829-2832. DOI: 10.1016/S0040-4039(99)00271-3


61. 2-alkylcyclobutanones as markers for irradiated foodstuffs. III. Improvement of the field of application on the EN 1785 method using silver ion chromatography.
B. Ndiaye, P. Horvatovitch, M. Miesch, C. Hasselmann, E. Marchioni J. Chrom. A, 1999, 858, 109-115. DOI: 10.1016/S0021-9673(99)00800-6


60. Uncatalyzed [2+2] cycloaddition of cyclic ketenetrimethylsilylacetals with electrophilic acetylenes.
M. Miesch, F. Wendling, M. Franck-Neumann Tetrahedron Lett., 1999, 40, 839-842. DOI: 10.1016/S0040-4039(98)02534-9


59. 2-alkylcyclobutanones as markers for irradiated foodstuffs. II. The CEN (european committee for standardization) method: field of application and limit of utilization.
B. Ndiaye, G. Jamet, M. Miesch, C. Hasselmann, E. Marchioni Radiat. Phys. Chem. 1999, 55, 437-445. DOI: 10.1016/S0969-806X(99)00198-X


58. 2-alkylcyclobutanones as markers for irradiated foodstuffs. I. Synthesis of saturated and unsaturated standarts.
M. Miesch, B. Ndiaye, C. Hasselmann, E. Marchioni Radiat. Phys. Chem.1999, 55, 337-344. DOI: 10.1016/S0969-806X(98)00338-7

1998
57. Diene tricarbonyl iron complexes bearing a free diazo group. III. Synthesis of pyrazoles and chiral complexes with α aminoacid or dienylcyclopropane substructures by 1,3-dipolar cycloaddition reactions.
M. Franck-Neumann, P. Geoffroy, A. Winling Tetrahedron Lett. 1998, 39, 5643. DOI: 10.1016/S0040-4039(98)01097-1


56. Synthesis and reactivity of Michael adducts of cyclic β-ketoesters and electrophilic acetylenes.
M. Miesch, G. Mislin, M. Franck-Neumann Tetrahedron Lett., 1998, 38, 6873-6876. DOI: 10.1016/S0040-4039(98)01500-7

1997
55. Synthesis of [α-alkyl β-hydroxy diene] Iron tricarbonyl complexes of known configurations via trisubstituted epoxides for the synthesis of polyenic macrolactones.
M. Franck-Neumann, C. Gateau, L. Miesch-Gross Tetrahedron Lett., 1997, 38, 8077-8080. DOI: 10.1016/S0040-4039(97)10112-5


54. Two carbon ring expansion by photochemical ring opening of electrophilic cyclobutenes.
M. Miesch, G. Mislin, M. Franck-Neumann Tetrahedron Lett., 1997, 38, 7551-7554. DOI: 10.1016/S0040-4039(97)10032-6


53. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes. 4. Enantioselective totale synthesis of 3-deoxypensoses from (-)myrtenal.
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4477. DOI: 10.1016/S0040-4039(97)00906-4
 

52. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes. 3. Enantioselective total synthesis of 3,6-dideoxyhexoses from lactaldehyde.
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4473. DOI: 10.1016/S0040-4039(97)00905-2


51. Aldol condensation reactions of chiral (dienone) tricarbonyliron complexes. 2. Enantioselective synthesis of the dienic polyols streptenols C and D (Metabolites from Streptomyces Fimbriatus).
M. Franck-Neumann, P. Bissinger, P. Geoffroy Tetrahedron Lett. 1997, 38, 4469. DOI: 10.1016/S0040-4039(97)00904-0
 

50. Total synthesis of (±)-pentalenene via small ring intermediates.
M. Miesch, L. Miesch-Gross, M. Franck-Neumann Tetrahedron, 1997, 53, 2111-2118. DOI: 10.1016/S0040-4020(96)01160-X


49. Total synthesis of (±)-silphinene : non photochemical cyclobutenic route to a crucial intermediate.
M. Miesch, L. Miesch-Gross, M. Franck-Neumann Tetrahedron, 1997, 53, 2103-2110. DOI: 10.1016/S0040-4020(96)01159-3

1996
48. Intramolecular Friedel-Crafts acylations of 1- and 2-alkanoic acid diene tricarbonyliron complexes.
M. Franck-Neumann, L. Miesch-Gross, O. Nass Tetrahedron Lett., 1996, 37, 8763-8766. DOI: 10.1016/S0040-4039(96)02044-8


47. Access to the bicyclo[5.3.1]undecadiene ring system by two carbon ring enlargement of bicyclo[3.3.1]nonane derivatives.
M. Miesch, G. Mislin, M. Franck-Neumann Synlett, 1996, 385-386. DOI: 10.1055/s-1996-5414

1995
46. Tricarbonyl Iron complexes bearing a free diazo group. II. Diene and trimethylenemethane diazoketon complexes as precursors of highly reactive ketocarbenes and diazonium cations.
M. Franck-Neumann, P. Geoffroy, A. Winling Tetrahedron Lett. 1995, 36, 8213. DOI: 10.1016/0040-4039(95)01757-9


45. Tricarbonyl iron complexes bearing a free diazo group. I. Synthesis and cyclocarbonylation reactions of α-diazodiene complexes.
M. Franck-Neumann, P. Geoffroy, A.Winling Synlett 1995, 341. DOI: 10.1055/s-1995-4960


44. Synthèse de diquinanes fonctionnalisés par l'intermédiaire de cyclobutènes électrophiles.
M. Franck-Neumann, M. Miesch, L. Gross Tetrahedron, 1995, 51, 4969-4984. DOI: 10.1016/0040-4020(95)98694-D

1994
43. Total synthesis of (±) Stoechospermol.
M. Miesch, A. Cotté, M. Franck-Neumann Tetrahedron Lett., 1994, 35, 7031-7032. DOI: 10.1016/0040-4039(94)88217-7


42. Synthesis of dienic α-ketoesters by Friedel-Crafts reaction of ethyl oxalyl chloride with tricarbonyl iron complexes of E- and Z- substituted acyclic dienes.
M. Franck-Neumann, P. Geoffroy  Tetrahedron Lett. 1994, 35, 7027. DOI: 10.1016/0040-4039(94)88216-9

1993
41. Non photochemical synthesis of condensed cyclobutenes. Synthesis of the cis-anti-cis tricyclo [5.3.0.02,6] decane skeleton.
M. Miesch, A. Cotté, M. Franck-Neumann Tetrahedron Lett., 1993, 34, 8085-8086. DOI: 10.1016/S0040-4039(00)61457-0


40. One-carbon Friedel-Crafts functionalizations of acyclic diene iron tricarbonyl complexes.
M. Franck-Neumann, P. Bissinger, P. Geoffroy  Tetrahedron Lett. 1993, 34, 4643. DOI: 10.1016/S0040-4039(00)60645-7


39. Synthesis of polyquinanes via bicyclo [2.1.0] pentane intermediates. An easy access to optically pure diquinane alcohols of known absolute configuration.
M. Franck-Neumann, M. Miesch, A. Cotté, L. Gross, B. Metz Tetrahedron Asymm., 1993, 4, 2475-2484. DOI: 10.1016/S0957-4166(00)82226-0


38. Synthèse totale de la dihydro-2,3-Illudine M par cycloaddition d'énamine sur cyclopropène.
M. Franck-Neumann, M. Miesch, F. Barth Tetrahedron, 1993, 49, 1409-1420. DOI: 10.1016/S0040-4020(01)90193-0

1992
37. The aldol condensation reaction of diene (tricarbonyl) iron complexes. From metal coordinated trimethylsilyl enol ethers to polyols of known configuration.
M. Franck-Neumann, P.J. Colson, P. Geoffroy, K.M. Taba  Tetrahedron Lett. 1992, 33, 1903. DOI: 10.1016/S0040-4039(00)74173-6


36. High pressure dimerization of a gem-disubstituted cyclopropene. Evidence of cyclopropene-vinylcarbene equilibrium.
M. Miesch, F. Barth, M. Franck-Neumann, G. Jenner Recent Trends in High Press. Res. (A.K. Singh Ed.) Oxford and IBH Pub. New Dehli, 1992, 553-555.


35. Cycloaddition eines sehr reaktiven Cyanovinylcarbens mit Benzol und 3,4-Dichlorcyclobuten Molekular- und Kristallstruktur von 2,3-Dichlor-5-(1-cyano-2-methyl-1-propenyl)-5-hausancarbonitril und 7-(1-cyano-2-methyl-1-propenyl)-7-norcaradiencarbonitril.
M. Franck-Neumann, M. Miesch, S. Gries, H. Irngartinger Liebigs Ann. Chem., 1992, 825-829. DOI: 10.1002/jlac.1992199201136


34. Synthesis of the angular triquinane (±) Pentalenene via small ring intermediates.
M. Franck-Neumann, M. Miesch, L. Gross Tetrahedron Lett., 1992, 33, 3879-3882. DOI: 10.1016/S0040-4039(00)74809-X


33. Accès au squelette triquinanique linéaire par l'intermédiaire de dérivés bicyclo [2.1.0] pentaniques. Synthèse totale d'un triquinane, le (±) Hirsutène.
M. Franck-Neumann, M. Miesch, E. Lacroix, B. Metz, J.M. Kern Tetrahedron, 1992, 48, 1911-1926. DOI: 10.1016/S0040-4020(01)88514-8

1991
32. Alkynes and poly (ethylene glycol) derivatives as nucleophiles and catalysts in substitution reactions of 1-chloroanthraquinones.
J. Fang, T. Lu, H. Kim, I. Delgado, P. Geoffroy, J.L. Atwood, G.W. Gokel J. Org. Chem. 1991, 56, 7059. DOI: 10.1021/jo00025a021


31. The cyclobutenic way to triquinanes. Total synthesis of (±) Silphinene.
M. Franck-Neumann, M. Miesch, L. Gross Tetrahedron Lett., 1991, 32, 2135-2136. DOI: 10.1016/S0040-4039(00)71256-1

1990
30. Synthesis and bronchospasmolytic effects of benzocyclobutenic and benzocyclenic compounds.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, A. Mouaddib, A.A Aatif, M.A. Zouaoui, P. Caubère, M. Blanc, J.P. Gnassounou, C. Advenier  Eur. J. Med. Chem. 1990, 25, 441.
DOI: 10.1016/0223-5234(90)90008-Q

29. Structures of two products of arynic condensation of ketone enolates.
S. Ianelli, M. Nardelli, D. Belletti, P. Geoffroy, M.C. Carré, M. Mouaddib, P. Caubère  Acta Crystallogr., sect C. Crystal Struct. Com. 1990, C46 7, 1318-1324. DOI: 10.1107/S0108270189009108


28. The bicyclo [2.1.0] pentane way to the diquinane alcohol part of natural triquinanes. A high yield access starting from trimethylsilyloxycyclopentane.
M. Franck-Neumann, M. Miesch, L. Gross Tetrahedron Lett., 1990, 31, 5027-5030. DOI: 10.1016/S0040-4039(00)97796-7

27. Convergent syntheses in the sesquicarene series using a C7-vinylalkynylcarbene.
M. Franck-Neumann, P. Geoffroy, M. Miesch, F. Zaragosa Dörwald Tetrahedron Lett., 1990, 31, 4121-4124. DOI: 10.1016/S0040-4039(00)97558-0

1989
26. Cistulynes : proton NMR and single-crystal X-ray evidence for structure and cation encapsulation in a rigid, molecular channel model system.
A. Nakano, Y. Li, P. Geoffroy, M. Kim, J.L. Atwood, S. Bott, H. Zhang, L. Echegoyen, G.W. Gokel  Tetrahedron Lett. 1989, 30, 5099-5102. DOI:  10.1016/S0040-4039(01)93457-4


25. Arynic condensation of nitrile anions in the presence of the complex base NaNH2-CH3CH2(OCH2CH2)2ONa.
M.C. Carré, A.S. Ezzinadi, M.A. Zouaoui, P. Geoffroy, P. Caubère  Synth. Comm. 1989, 19, 3323-3330. DOI: 10.1080/00397918908052735


24. New easy access to benzocyclobutenones derivatives.
M.A. Zouaoui, M.C. Carré, B. Jamart-Groigoire, P. Geoffroy, P. Caubère Tetrahedron 1989, 45, 5485-5496. DOI: 10.1016/S0040-4020(01)89495-3


23. Arynic condensations of ketone enolates 20. New access to polycyclic phenylethanolamines.
M.C. Carré, A.A. Aatif, P. Geoffroy, P. Caubère  Synthetic Comm. 1989, 19, 2523-2550. DOI: 10.1080/00397918908052655


22. Structural influence of the ortho-peri-condensed cycloalkane rings on the conformation of 2-(hydroxyalkyloxy)indanone cyclisation products.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, P. Caubère, S. Ianelli, M. Nardelli Acta Cryst. B 45 1989, 2, 178. DOI: 10.1107/S0108768188012947

21. De l'instabilité des cyclopropènes à double liaison fonctionnalisée monosubstituée. Equilibre non photochimique entre cyclopropènes et vinylcarbènes.
M. Franck-Neumann, M. Miesch, F. Barth, G. Jenner Bull. Soc. Chim. Fr.
, 1989, 661-666.

20. A simple synthesis of a new family of polycyclic oxygen containing heterocycles. P. Geoffroy, M.C. Carré, P. Caubère, S. Ianelli, M. Nardelli. J. Heterocyclic Chem. 1989, 26, 65-69. DOI: 10.1002/jhet.5570260113

19. Cyclopropene als C3-Synthesebausteine : Cyclopentenole und grosse Ringe aus 2-Aminobicyclo [2,1,0] pentan-Derivaten über Ringerweiterungs-reaktionen.
M. Franck-Neumann, M. Miesch, H. Kempf Synthesis, 1989, 820-824. DOI: 10.1055/s-1989-27401


18. Synthèse cyclopropénique de dérivés de l'Illudine M.
M. Franck-Neumann, M. Miesch, F. Barth Tetrahedron Lett., 1989, 30, 3537-3540.DOI: 10.1016/S0040-4039(00)99433-4


17. Synthèse cyclopropénique totale d'un triquinane naturel angulaire, le (±)-Silphinène.
M. Franck-Neumann, M. Miesch, E. Lacroix Tetrahedron Lett., 1989, 30, 3533-3536. DOI: 10.1016/S0040-4039(00)99432-2


16. Synthèse cyclopropénique totale d'un triquinane naturel linéaire, le (±)-Hirsutène.
M. Franck-Neumann, M. Miesch, E. Lacroix Tetrahedron Lett., 1989, 30, 3529-3532. DOI: 10.1016/S0040-4039(00)99431-0

1988
15. Structural influence of the ortho-peri-condensed cycloalkane rings on the conformation of 2-(hydroxyalkyloxy)indanone cyclisation products.
P. Geoffroy, M.C. Carré, B. Jamart-Grégoire, P. Caubère, S. Ianelli, M. Nardelli  Z. Kristallographie 1988, 185, 239.

14. Arynic condensation of ketone enolates 19. Synthesis of polycyclic phenylethanolamines.
P. Geoffroy, A. Mouaddib, M.C. Carré, P. Caubère  Tetrahedron Lett. 1988, 29, 1385-1388. DOI: 10.1016/S0040-4039(00)80303-2


13.Cyclopropènes électrophiles : réactions du morpholino-1 cyclohexène avec quelques esters gem-diméthylcyclopropéniques ; accès à des analogues halopyréthriques (1).
M. Franck-Neumann, M. Miesch, H. Kempf Tetrahedron, 1988, 44, 2933-2942. DOI: 10.1016/S0040-4020(88)90030-0

12. Réactions de cyclobutènes électrophiles avec les énamines. Facteurs déterminant l'obtention de dérivés bicyclo[2.2.0] hexaniques.
M. Franck-Neumann, M. Miesch, F. Barth Tetrahedron, 1988, 44, 417-428. DOI: 10.1016/S0040-4020(01)85833-6

11. Arynic condensation of ketone enolates 18. Efficient access to benzocyclenones and polycyclic indanone derivatives.
M.C. Carré, B. Jamart-Grégoire, P. Geoffroy, P. Caubère, S. Ianelli, M. Nardelli  Tetrahedron 1988, 44, 127-137. DOI: 10.1016/S0040-4020(01)85100-0
 

1987
10. Synthèse stéréospécifique de cis-pyréthroïdes par voie cyclopropénique utilisant un synthon carbanionique. II. Accès aux dérivés cis-chrysanthémiques et cis-pyréthriques.
M. Franck-Neumann, M. Miesch, H. Kempf Tetrahedron, 1987, 43, 853-858. DOI: 10.1016/S0040-4020(01)90022-5

9. Synthèse stéréospécifique de cis-pyréthroïdes par voie cyclopropénique utilisant un synthon carbanionique. I. Obtention de gem-diméthylpyrazolénines.
M. Franck-Neumann, M. Miesch, H. Kempf Tetrahedron, 1987, 43, 845-852. DOI: 10.1016/S0040-4020(01)90021-3

1986
8. Réactions de cyclopropènes électrophiles avec les énamines et ynamines. Cycloadduits bicyclopentaniques et analogues halochrysanthémiques.
M. Franck-Neumann, M. Miesch, H. Kempf Tetrahedron Lett., 1986, 27, 5215-5218.

7. Hot-guest complexation. 40. Synthesis and complexation of macrocyclic hosts containing cyclic ureas, anisyls and steric barriers.
K.D. Stewart, M. Miesch, C.B. Knobler, E.F. Maverick, D.J. Cram J. Org. Chem., 1986, 51, 4327-4337. DOI: 10.1021/jo00373a001

1984
6. Nitrovinylcarbenes : photolysis of the 3H-pyrazole precursors, intramolecular evolution and intermolecular reactivity.
M. Franck-Neumann, M. Miesch Tetrahedron Lett., 1984, 25, 2909-2912. DOI: 10.1016/S0040-4039(01)81323-X


5. Cycloaddition 1,3-dipolaire du diméthyldiazométhane sur des esters et nitriles polyéniques. Accès aux esters cis et trans chrysanthémiques à partir des esters -méthylsorbiques Z et E.
M. Franck-Neumann, M. Miesch Bull. Soc.
Chim. Fr., 1984, II, 362-370.

1983
4. Transpositions et réactions intermoléculaires de vinylalcynylcarbènes.
M. Franck-Neumann, P. Geoffroy  Tetrahedron Lett. 1983, 24, 1779-1782. DOI: 10.1016/S0040-4039(00)81768-2


3. Additions-1,3 dipolaires du diazo-2 propane sur le diacétylène et évolution photochimique des 3H-pyrazoles formés.
M. Franck-Neumann, P. Geoffroy, J.J. Lohmann  Tetrahedron Lett. 1983, 24, 1775-1778. DOI: 10.1016/S0040-4039(00)81767-0


2. Synthèse de diméthyl-5,5 pyrazolénines précurseurs de vinylcarbènes isoprénoïdes par oxydation directe de Δ
2 -pyrazolines.
M. Franck-Neumann, M. Miesch Tetrahedron, 1983, 39, 1247-1254. DOI: 10.1016/S0040-4020(01)91889-7

1982
1. Stereospecific cyclopropenic synthesis of cis-chrysanthemic methyl ester 2. The by-passing diazoalkane way.
M. Franck-Neumann, M. Miesch Tetrahedron Lett., 1982, 23, 1409-1412. DOI: 10.1016/S0040-4039(00)87119-1